Ambrosio is known for her work with Victoria's Secret and was chosen as the first spokesmodel for the company's PINK line.
Ambrosio was a Victoria's Secret Angels from 2000 to 2017 and has modeled for brands such as Next, Armani Exchange, Christian Dior, and Ralph Lauren.
The duo has two children; the first one is Anja Louise Ambrosio Mazur and the second one is Noah Phoenix Ambrosio Mazur.
Even being engaged for one decade, the couple has not shared about their marriage plan.
The couple got engaged back in 2008 and have two kids together, 5-year-old son Noah and 9-year-old daughter Anja.
While Alessandra and Jamie have yet to publicly address their split, the last time we saw them on a red carpet together was at the Baby2Baby Gala in November 2017.
She has appeared in numerous international magazine covers, including Cosmopolitan, Elle, GQ, Harper's Bazaar, Marie Claire, Ocean Drive, Vogue and was the only model to appear on the cover of Glamour in the United States in 2006.
In 2012, Ambrosio was chosen to wear the "Fantasy Bra".